NIST Technicalendar June 8 to June 12, 2009 The NIST Technicalendar is issued each Friday. All items MUST be submitted electronically from this web page by 12:00 NOON each Wednesday unless otherwise stated in the NIST Technicalendar. The address for online weekly editions of the NIST Technicalendar and NIST Administrative Calendar is: http://www.nist.gov/tcal.

In this Issue: Meetings at NIST Meetings Elsewhere Announcements Talks by NIST Personnel NIST Web Site Announcements NIST Administrative Calendar (current)   NIST Vacancy Announcements (current)

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9:00 AM - Cryptographic Key Management Workshop
10:45 AM - Complex Borohydrides as Hydrogen Storage Candidates
2:00 PM - BFRL Introduction to NIST's Center for Nanoscale Science and Technology and the NanoFab

8:30 AM - Visiting Committee on Advanced Technology (VCAT) Meeting
10:30 AM - RFID Performance in Rough Duty Environments
1:00 PM - Webinar: Measurement Needs for Advanced Biofuels

10:45 AM - In the Beginning: the early development of neutron stress measurements
11:00 AM - Hierarchical Bayesian Spatio-Temporal Models for Environmental Processes: PDE-Based Dynamics and Efficient Parameterizations

10:30 AM - Progress towards silicon germanium quantum dots
2:00 PM - Exciton dissociation in blends of fullerenes with conjugated polymers: Advancing organic solar cells through basic research
3:30 PM - NANOMAGNETISM: What Is It? Why Should We Care?

No Scheduled Events

6/8 -- MONDAY

9:00 AM - COMPUTER SECURITY DIVISION SEMINAR: Cryptographic Key Management Workshop
Key management is a fundamental part of cryptographic technology and is considered the most difficult aspect associated with its use. Of particular concern are the scalability of the methods used to distribute keys and the usability of these methods. NIST is undertaking an effort to improve the overall key management strategies used by the public and private sectors in order to enhance usability of cryptographic technology, provide scalability across all cryptographic technologies, and support a global cryptographic key management infrastructure.
Admiral Mike McConnell, Booz Allen Hamilton , Senior Vice President and former Director of National Intelligence. Dr. George Strawn, National Science Foundation , Chief Information Officer. Dr. Vint Cerf, Google, Vice President & Chief Internet Evangelist Dr. Silvia Micali, MIT, Dugald C. Jackson Professor of Computer Science
Administration Bldg, Green Auditorium. (NIST Contact: Sara Caswell, 301-975-4634, sara@nist.gov) http://www.csrc.nist.gov/groups/ST/key_mgmt/

10:45 AM - NIST CENTER FOR NEUTRON RESEARCH SEMINAR: Complex Borohydrides as Hydrogen Storage Candidates
Materials that are light weight, low cost and have high hydrogen storage capacity are essential for on-board vehicular applications. Some reversible complex hydrides are alanates and amides but they have lower capacity than the DOE target (6.0 wt %) for 2010. High capacity, light weight, reversibility and fast kinetics at lower temperature are the primary desirable aspects for any type of hydrogen storage material. Borohydride complexes as hydrogen storage materials have recently attracted great interest. Understanding the above parameters for designing efficient complex borohydride materials requires modeling across different length and time scales. A direct method lattice dynamics approach using ab initio force constants is utilized to calculate the phonon dispersion curves. This allows us to establish stability of the crystal structure at finite temperatures. Density functional theory (DFT) is used to calculate electronic properties and the direct method lattice dynamics is used to calculate the finite temperature thermodynamic properties. These computational simulations are applied to understand the crystal structure, nature of bonding in the complex borohydrides and mechanistic studies on doping to improve the kinetics and reversibility, and to improve the hydrogen dynamics to lower the decomposition temperature. A combined theoretical and experimental approach can better lead us to designing a suitable complex material for hydrogen storage. To understand the structural, bulk properties and the role of dopants and their synergistic effects on the dehydrogenation and/or reversible rehydrogenation characteristics, these complex hydrides are also studied experimentally. Both theoretical and experimental results will be presented.
Pabitra Choudhury , USF, Tampa.
235 Bldg, Rm. E100. (NIST Contact: Taner Yildirim, 301-975-6228, taner@nist.gov)

2:00 PM - CNST OUTREACH SERIES: BFRL Introduction to NIST's Center for Nanoscale Science and Technology and the NanoFab
This meeting with the Building and Fire Research Laboratory is part of a series of presentations to introduce the staff to NIST's newest operating unit, the Center for Nanoscale Science and Technology (CNST). An overview of the CNST will be presented which will provide a brief description of CNST's structure, which consists of both a research program and the NanoFab, a shared-use nanofabrication and nanoscale measurement facility. A strong bias toward collaborative work being among CNST's prime attributes, the overview will describe how NIST staff can go about collaborating with scientists in the research program or make use of the NanoFab. The NanoFab, which provides economical access to a wide variety of advanced lithography and microscopy tools, will be described. Examples of recent nanofabrication projects will be used to illustrate our capabilities. Finally, the process for becoming a NanoFab user or having a nanostructure made or measured for you will be outlined. The Laboratory by laboratory series of presentations has been designed to allow significant time to answer questions and tours will be arranged.
Robert Celotta , Director of CNST. Alex Liddle and Vincent Luciani of CNST
Bldg. 224, Rm. B245. (NIST Contact: Lloyd Whitman, 301-975-8002, lloyd.whitman@nist.gov)


6/9 -- TUESDAY

8:30 AM - OFFICE OF THE DIRECTOR, NIST SEMINAR: Visiting Committee on Advanced Technology (VCAT) Meeting
Patrick Gallagher , Deputy Director, NIST.
Administration Bldg, Employees Lounge. (NIST Contact: Gail Ehrlich, 301-975-2149, gail.ehrlich@nist.gov) http://www.nist.gov/director/vcat/agenda.htm

10:30 AM - FIRE RESEARCH DIVISION SEMINAR: RFID Performance in Rough Duty Environments
Radio frequency identification (RFID) tags have become widely used by industry and retail sales businesses for tracking materials, products, and inventories. This same technology is now being used by government agencies and is being studied for use by the United States emergency response community. This tracking technology may be applied to emergency responder apparatus, equipment, and human body worn tracking and locating systems. Currently, standards do not exist for the technology when it is applied by the emergency response community. The Building and Fire Research Laboratory (BFRL) has conducted a series of fire tests to evaluate rough duty performance. Passive and active RFID tag designs were studied. Test data indicate that some types of RFID tags are sensitive to elevated temperatures and exposure to water. Each of these factors is likely to impact the development of standards for RFID tags used by emergency responders.
J. Randy Lawson , Fire Fighting Technology Group, NIST/BFRL.
Bldg 224, Rm B245. (NIST Contact: Rodney Bryant, 301-975-6487, rodney.bryant@nist.gov)

1:00 PM - TECHNOLOGY SERVICES SEMINAR: Webinar: Measurement Needs for Advanced Biofuels
Measurements and standards are critical to all aspects of the biofuels industry, including the science of engineering new feedstocks, feedstock production and handling, biochemical and thermochemical conversion and refining processes, distribution and supply infrastructure, and end-use. The webinar will present the results of a preliminary assessment of measurement and standards needs for advanced biofuels in all these areas. Registration is FREE.
Clare Allocca , Chief, USMS Office, Gaitherbsurg, MD, clare.allocca@nist.gov. Chris Clarke , Energetics, Inc..
Materials Bldg, Rm. B307. (NIST Contact: Allan Eustis, 301-975-5099, allan.eustis@nist.gov) http://www.bostonconferencing.com/nist


6/10 -- WEDNESDAY

10:45 AM - NIST CENTER FOR NEUTRON RESEARCH SEMINAR: In the Beginning: the early development of neutron stress measurements
This is a tour through the history of stress measurements by means of neutron diffraction, presented by one of the first prospectors of the field.
Aaron Krawitz , U of Missouri.
Bldg. 235, E100 (Large Conf. room). (NIST Contact: Thomas Gnäupel-Herold, 301-975-5380, tg-h@nist.gov)

11:00 AM - STATISTICAL ENGINEERING DIVISION SEMINAR: Hierarchical Bayesian Spatio-Temporal Models for Environmental Processes: PDE-Based Dynamics and Efficient Parameterizations
Spatio-temporal dynamical processes in the physical and environmental sciences are often described by partial differential equations (PDEs). The inherent complexity of such processes due to high-dimensionality and multiple scales of spatial and temporal variability is often intensified by characteristics such as sparsity of data, complicated boundaries and irregular geometrical spatial domains, among others. In addition, uncertainties in the appropriateness of any given PDE for a real-world process, as well as uncertainties in the parameters associated with the PDEs are typically present. These issues necessitate the incorporation of efficient parameterizations of spatio-temporal models that are capable of addressing such characteristics. In this work, a hierarchical Bayesian model characterized by the PDE-based dynamics for spatio-temporal processes based on their Galerkin finite element method (FEM) representations is developed and discussed. As an example, spatio-temporal models based on advection-diffusion processes are considered. Finally, an application of the hierarchical Bayesian modeling approach is presented which considers the analysis of tracking data obtained from DST (data storage devices) sensors to mimic the pre-spawning upstream migration process of the declining shovelnose sturgeon.
Dr. Ali Arab , Department of Mathematics, Georgetown University.
222 Bldg, Rm. A326. (NIST Contact: Charles Hagwood, 301-975-2846, hagwood@nist.gov)


6/11 -- THURSDAY

10:30 AM - CNST ENERGY RESEARCH GROUP SEMINAR: Progress towards silicon germanium quantum dots
Abstract: Measurements are described on Silicon Germanium (SiGe) two dimensional electron gasses (2DEGs) and quantum dots, with the goal of using these materials to form solid state quantum bits. The role of strain fields arising from misfit dislocations is discussed, along with the influence of excess dopant atoms in the donor layer. Quantum dots are fabricated using a shallow etch technique, and coulomb blockade diamonds are seen in these devices. Bio: Ian Gelfand recently completed his Ph.D. in Applied Physics at Harvard University. His research focus was on low temperature Condensed Matter experiments, and he performed this work in Marc Kastner's group at MIT. Over the course of his studies, Ian worked extensively with silicon germanium two dimensional electron gases (2DEGs) and quantum dots, and worked with InAs 2DEGs. Additionally he did detailed studies of the Kondo effect in quantum dots. Prior to graduate school, Ian was a Fulbright Scholar in Tuebingen, Germany, where he worked in the Dieter Kern's group. Ian received his bachelor's degree from the University of Pennsylvania where he did a long thesis project on carbon nanotubes in the group of A.T. "Charlie" Johnson, a former NIST NRC postdoc.
Ian Gelfand , Applied Physics, Harvard University.
Bldg. 217, Rm. H107. (NIST Contact: Fred Sharifi, 301-975-4633, fred.sharifi@nist.gov)

2:00 PM - POLYMERS DIVISION SEMINAR: Exciton dissociation in blends of fullerenes with conjugated polymers: Advancing organic solar cells through basic research
Photovoltaic solar cells based on organic systems are considered an emerging and viable technology, with respectable device performance characteristics and lifetimes. Common to almost all of these new devices is a nanostructured interface that comprises a donor, often a conjugated polymer such as poly (3-hexylthiophene), and more often than not, C60 as an acceptor. A unique and essential feature of these interfaces is the ability to efficiently dissociate the photo-generated excitons into free carriers and, more importantly, to very effectively inhibit the reverse, recombination process. A uniform consensus on why this happens has yet to emerge and it is therefore a topic of great interest. Although they are considered to be a viable technology, solar cell performances are struggling to exceed 5% power conversion efficiencies, and there is a need to increase this value significantly. To do so, requires more fundamental, basic research to be focused on the problem, and this approach is what motivates this presentation. The first part of the seminar will discuss these low device performance efficiencies, their importance, how they might be increased, and how they compare with more conventional photovoltaic devices. The second part of the presentation will focus on the use of timeresolved microwave conductivity using pulsed laser excitation, as a tool for probing both the production and loss of free carriers that result from exciton dissociation. Foundational data on the ubiquitous P3HT:PCBM system will be presented examining a number of loss mechanisms that plague the production of excitons and their efficient transport of the free carriers through the system. Finally, a discussion of the role that single-wall carbon nanotubes (SWNTs) might play not only as a suitable replacement for PCBM as an electron acceptor and transporter, but also as a near-IR absorber.
Garry Rumbles , Research Fellow, National Renewable Energy Laboratory, Golden, CO.
224 Bldg, Rm. A312. (NIST Contact: Dean DeLongchamp, 301-975-5599, deand@nist.gov)

3:30 PM - SURF SUMMER SEMINAR SERIES: NANOMAGNETISM: What Is It? Why Should We Care?
As has been found for many other properties, the magnetic character of materials possessing some material dimension in the nanometer regime can be quite different from that commonly associated with conventional macro-scaled materials. New magnetic phenomena, unusual property combinations, and both enhanced and diminished magnetic property values are just some of the changes observed. As a consequence, these materials are being investigated for their potential as the next generation soft ferromagnets in addition to their future as pioneeered hard ferromagnets with vastly improved energy products. Why that is the case and why you should care will be presented here. In addition, the unique domain kinetics, the "Giant Magnetoresistance (GMR)" effects, and the "Enhanced Magnetocaloric Effects" of this class of materials will also be described. These nanostructured materials are one of the reasons for the excitement surrounding the "Nanotechnology Revolution" that has presently captured the imagination of the world.
Dr. Robert Shull , Group Leader, Magnetic Materials Group, Materials Science & Engineering Laboratory.
Administration Bldg, Green Auditorium. (NIST Contact: Anita Sweigert, 301-975-4201, anita.sweigert@nist.gov)
Special Assistance; Contact A. Sweigert a week in advance.


6/12 -- FRIDAY

No Scheduled Events

ADVANCE NOTICE

6/16/09 10:30 AM - ATOMIC PHYSICS DIVISION SEMINAR: Anisotropic Plasma Etching of Si/SiGe Heterostructures and Induced Sidewall Damage
Ruhang Ding , Spansion.
Physics Building, Room B145. (NIST Contact: Neil Zimmerman, 301-975-5887, neil.zimmerman@nist.gov)

6/18/09 10:30 AM - CNST ELECTRON PHYSICS GROUP SEMINAR: APPLYING NANOTRIBOLOGY TO MICRO AND NANOMECHANICAL DEVICES
The reduced length scale of contacts in micro- and nano-electromechanical systems (M/NEMS) and atomic force microscopy (AFM)-based applications leads to tremendous increases in contact stresses, adhesive interactions, friction, tribochemical reactions, and wear. These phenomena are yet to be well-understood or controlled, creating a critical scientific challenge for the development and commercialization of these micro- and nano-technologies. I will discuss specific applications where these factors are critical, including nanomanufacturing, nanomechanical data storage, and MEMS and NEMS switches. I will then discuss experimental methodologies for measuring and understanding nanoscale tribology through combinations of AFM, other microscopies, and surface spectroscopic techniques. I will then highlight recent measurements that demonstrate how nanotribological phenomena are related to surface atomic bonding and environmental conditions. Particular emphasis will be placed on how the use of materials with excellent macroscopic tribo-mechanical properties, including diamond and diamond-like films, can provide dramatic improvements compared with silicon-based materials which are more commonly used in nanoscale applications currently.
Robert Carpick , Director, The Nanotechnology Institute, University of Pennsylvania.
Bldg.217, Rm.H107. (NIST Contact: Rachel Cannara, 301-975-4258, rachel.cannara@nist.gov)

6/22/09 10:30 AM - CNST ELECTRON PHYSICS GROUP SEMINAR: CATALYTIC CVD GROWTH OF CARBON NANOTUBES AND THEIR APPLICATION AS CHEMICAL SENSORS
Carbon based materials come in a variety of different forms that depend on how their atoms link together, such as zero-dimensional fullerenes, one-dimensional nanotubes, two-dimensional (2-D) graphene and three-dimensional (3-D) graphite. The properties of these carbon based materials can be tailored by irradiation and chemical functionalization to use them for various applications. In recent years, carbon nanotubes (CNTs) have been a subject of increased interest especially because of their exceptional thermal, electrical and mechanical properties which far exceed those of most bulk materials. However inspite of considerable progress in the synthesis of CNTs there still exist significant challenges like production of nanotube materials with controlled diameter, length, orientation, location and microstructure. Thus there is a need to understand the growth mechanisms of both multiwalled and singlewalled carbon nanotubes in order to synthesize them in a controlled manner. The high electrical conductivity and surface area of CNTs is motivating their application as chemical sensors. We present here a systematic study of molecular adsorption on SWNTs by measurements of the conductivity response of single walled carbon nanotube (SWNT) arrays to trace vapors for a range of linear chain and aromatic molecules. Ab initio calculations were performed with density functional theory methods to investigate the molecular adsorption of these molecules on SWNTs. Both conductance measurements and Ab initio calculations show that the adsorption energies of linear alkane, alcohol and ketone molecules increase linearly with the length of the molecule. These results indicate that the initial adsorption and conductivity response occurs with molecules predominantly lying flat on the defect-free nanotube side walls and the long time response is dominated by adsorption at defects. The difference in the conductivity responses for polar and non polar adsorbates is attributed to changes in scattering due to adsorbates. Further experiments with random arrays of carbon nanotubes reveal a strong conductivity response after exposure to aromatic molecules containing nitro functional groups, such as nitrobenzene and trinitrotoluene. Ab initio calculations also show a strong increase in adsorption energy with the addition of each nitro group to a molecule (around 100 meV) and a gradual increase with nanotube size, in agreement with preliminary experimental results. Finally, these calculations are compared with results for the adsorption at oxidation defects.
Navdeep Bajwa , Postdoctoral Fellow, The US Naval Research Laboratory.
Bldg.217, Rm.H107. (NIST Contact: Rachel Cannara, 301-975-4258, rachel.cannara@nist.gov)

6/26/09 11:00 AM - CNST ELECTRON PHYSICS GROUP SEMINAR: NANOSCALE TEMPERATURE RISE AND MELTING AT A RUBBING INTERFACE
Temperature rise, and the associated effects of softening and/or melting, of a sliding asperity contact impacts a broad range of fundamental and applied topics--from nano- and micro-electromechanical systems to frictional behavior at geological faults. Despite great importance, however, a fundamental understanding of the interfacial and chemical processes that occur in such contacts is lacking. By utilizing the unique capabilities of a combined scanning tunneling microscope and quartz crystal microbalance, the velocity dependent morphology of a single asperity contact is able to be probed. The results give intriguing evidence for a velocity dependent transition from a solid interface to a liquid-like interface, the first such observation for a sliding asperity contact.
Benjamin Dawson , Ph.D. Candidate, North Carolina State University.
Bldg.217, Rm.H107. (NIST Contact: Rachel Cannara, 301-975-4258, rachel.cannara@nist.gov)

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MEETINGS ELSEWHERE


6/8 -- MONDAY

No Scheduled Events

6/9 -- TUESDAY

11:00 AM - CARNEGIE INSTITUTION OF WASHINGTON/GEOPHYSICAL LAB. SEMINAR: THE NEW PARADIGM OF HIGH-PRESSURE SCIENCE
H-K (Dave) Mao , GL.
Bldg, Rm..
Greenewalt Bldg., GL-DTM Grounds, Carnegie Institution of Washington, DC. (NIST Contact: A. Goncharov, 202-478-8900, seminar@lists.ciw.edu)



6/10 -- WEDNESDAY

No Scheduled Events

6/11 -- THURSDAY

No Scheduled Events

6/12 -- FRIDAY

No Scheduled Events

ADVANCE NOTICE

No Scheduled Events

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TALKS BY NIST PERSONNEL

ROSADO-REYES, C. : H ATTOM ATTACK ON PROPENE: COMPARISON WITH PROPYNE.
6th Mediterranean Combustion Symposium/The Combustion Institute, Portoccio-Ajaccio, Corsica (France), 6/8.

POTRA, F. : SEMI-INFINITE PROGRAMMING IN MULTI-HAZARD STRUCTURAL DESIGN.
Eleventh International Conference on Optimum Design of Structures and Materials in Engineering (OPTI 2009), Algarve, Portugal, 6/9.

RUST, B. : MODELING ATMOSPHERIC RETENTION OF MAN-MADE CO2 EMISSIONS.
MAMERN '09: International Conference on Approximation Methods and Numerical Modeling in Environment and Natural Resources, Pau, France, 6/9.

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ANNOUNCEMENTS

2009 RAC COLLOQUIUM SERIES: WHAT'S SO SMART ABOUT THE SMART GRID
Gaithersburg: June 18, 2009, 3:30 pm, Green Auditorium Boulder: July 23, 2009, 9:30 am, Boulder Auditorium David Wollman, Electronics and Electrical Engineering Laboratory By upgrading our existing electric power grid with two-way communications and advanced sensors, monitoring and control, the resulting Smart Grid will support increased use of renewable energy sources, allow more efficient and effective use of electricity, and reduce the potential for blackouts and power disturbances. In the Energy Independence and Security Act of 2007, NIST is charged with "primary responsibility to coordinate the development of a framework that includes protocols and model standards for information management to achieve interoperability of smart grid devices and systems...". This talk will help to explain what makes the Smart Grid unique, and why this topic is of great interest in the U.S. and around the world. NIST's Smart Grid efforts will be presented within the context of numerous challenges, including significant national visibility, bringing together multiple stakeholders with varying goals and objectives, and developing a standards roadmap to organize and accelerate standards development in the private sector to support and enable new Smart Grid technologies.
NIST Contact: Ajit Jillavenkatesa, 301-975-5089, ajit.jilla@nist.gov

S.T.E.M. TALENT 2009: CONFERENCE AND CAREER FAIR FOR POSTDOCS IN THE CAPITAL REGION
NIST is once again a sponsoring organization of this year's Postdoctoral event, "S.T.E.M. Talent 2009: Conference and Career Fair for Postdocs in the Capital Region". The event will take place on Wednesday, July 22, 2009, from 8:30 am – 3:30pm at the Montgomery County Conference Center, 5701 Marinelli Drive, Bethesda. The goals of the event are to: - connect qualified postdoctoral fellows with companies and organizations that have appropriate openings - provide postdocs with the advice and resources needed to secure a non-academic position - support Washington area businesses by building awareness of the postdoctoral resource - provide a benefit to participating organizations that they can cite in recruiting postdocs - provide a model of inter-organization collaboration - develop long-term relationships between federal laboratories and Washington area businesses and organizations We expect 400 – 500 job-seeking postdocs to participate in this year's career fair along with 30-40 hiring organizations. For additional information, please visit the web site at http://postdoc-conference.ncet2backoffice.org/ The Office of Technology Partnerships and the Office of International and Academic Affairs will be hosting a NIST booth in the Career Fair portion of the event. This is an excellent opportunity to provide information on your laboratory and position openings over the next six months to the best scientific talent in the area. Please contact Susan Heller-Zeisler (szeisler@nist.gov) or Terry Lynch (terry.lynch@nist.gov) with any information or position descriptions you would like to have disseminated. Of course, this is also a great opportunity for NIST post docs to meet with top employers in the area and we would appreciate you making them aware of the event and providing an opportunity to attend.
NIST Contact: Susan Heller-Zeisler, 301-975-3111, szeisler@nist.gov

PUBLICATIONS PRINTING DEADLINE AUGUST 14, 2009
August 14 is the last day in FY 2009 to submit materials using FY 2009 funds to the Electronic Information and Publications Group (EIPG) for printing at the Department of Commerce or Government Printing Office. To assure timely processing, bring your Editorial Review Board-approved document or administrative printing job and appropriate paperwork to the EIPG office by close of business on Friday, August 14, 2009. The office is located on the mezzanine floor of the NIST Research Library in the Administration Building, Room E220. Questions? Ilse Putman, x2780 or Barbara Silcox, x2146.
NIST Contact: Ilse Putman, 301-975-2780, ilse.putman@nist.gov

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NIST WEB SITE ANNOUNCEMENTS

No Web Site announcements this week.

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For more information, contact Ms. Sharon Hallman, Editor, Stop 2500, National Institute of Standards and Technology, Gaithersburg MD 20899-2500; Telephone: 301-975-TCAL (3570); Fax: 301-926-4431; or Email: tcal@nist.gov.

All lectures and meetings are open unless otherwise stated.

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